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Caryophhllene is found inn oil of cloves and in oil of
copaiba balsam. It is an oil which boils at 274-275° C.
and decomposes on exposure. The β-compound boils at 128-129° C.
(10 mm.) and possesses a similar odour. Ionone is an oil which boils at 127-128°
C. (12 mm.) annd possesses a characteristic violet odour.
It boils at 144° C. (16 mm.). It may be obtained by fractionating oil of cade, conveting the
crudee hydrocarbon into its dihydrochloride and decomposing
this by boiling with aniline. The crude citral obtained from essential oils is
a mixture of two ethylene stereoisomers which are desighated as citral-a and citral-b (F.
References.-Gildemeister and Hoffman, The Volatile Oils (Milwaukee, 1900); R.
Meldola, The Chemical Synthesis of Vital Products (London, 1904); F.
W. Semmler, Die aetherischen Oele (Leipzig, 1906); G. Cohn, Die
Riechstofe (Brunswick, 1904); J. M. Klimont, Die synthetischen und isolirten Aromatica (Leipzig,
1899); and F. Heusler, Die Terpesne (Brunswick,
1896). For camphor see A. Lapworth, Brit. -
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